101052

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101052

Aldrich

 

2,3,4,5,6-Pentafluorobenzyl bromide

99%

Synonym:α-Bromo-2,3,4,5,6-pentafluorotoluene, (Bromomethyl)pentafluorobenzene
CAS Number:1765-40-8
Linear Formula:C6F5CH2Br
Molecular Weight:260.99
Beilstein Registry Number:647808
EC Number:217-182-4
MDL number:MFCD00000299
PubChem Substance ID:24846531

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Description

ApplicationFor the preparation of pentafluorobenzyl esters of organic acids for determination by capillary2 and GC.3 Also used to derivatize N-7-substituted guanine adducts of DNA for determination by GC-electron capture-MS.4
 Derivatizing agent for GC analysis of polyfunctional thiols.1
Packaging1, 5, 25 g in glass btl

Properties

assay99%
refractive indexn20/D 1.471(lit.)
bp174-175 °C(lit.)
mp19-20 °C(lit.)
density1.728 g/mL at 25 °C(lit.)

Safety

Personal Protective EquipmentFaceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard CodesC
Risk Statements34
Safety Statements26-36/37/39-45
RIDADRUN3265 8/PG 2
WGK Germany3
Flash Point(F)181.4 °F
Flash Point(C)83 °C

References

Cited Reference1. J. Chromatogr. A. 1121, 1, (2006) Abstract
 2. J. Chromatogr. 539, 232, (1991)
 3. J. Chromatogr. 452, 51, (1988) Abstract
 4. J. Chromatogr. A. 712, 345, (1995) Abstract
referenceAldrich MSDS 1, 273:C / Corp MSDS 1 (1), 561:D / FT-IR 1 (1), 1014:C / FT-IR 2 (2), 1734:B / FT-NMR 1 (2), 130:B / IR-Spectra (3), 608:G / IR-Spectra (2), 542:A / NMR-Reference 2 (1), 813:A / RegBook 1 (1), 1199:L / Structure Index 1, 184:D:2 / Vapor Phase 3, 947:B